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1122 For one of the following, determine the ratio of the fugacity in the final state to that in the initial state for steam undergoing the isothermal change of state: (a) From 9000 kPa and 67315 K (400 C) to 300 kPa (b) From 7000 kPa and 700 K to 345 kPa 1123 Estimate the fugacity of one of the following liquids at its normal-boiling-point temperature and 200 bar: (a) n-Pentane; (b) Isobutylene; (c) 1-Butene 1124 Assuming that Eq (1165) is valid for the vapor phase and that the molar volume of saturated liquid is given by Eq (363), prepare plots of f vs P and of q5 vs P for one of the following: (a) Chloroform at 47315 K (200 C) for the pressure range from 0 to 40 bar At 47315 K (200 C) the vapor pressure of chloroform is 2227 bar (b) Isobutane at 31315 K (40 C) for the pressure range from 0 to 10 bar At 31315 K (40 C) the vapor pressure of isobutane is 528 bar 1125 For the system ethylene(l)/propylene(2) as a gas, estimate f l , f 2 , T/t = 42315 K (150"C), P = 30 bar, and yl = 035: (a) Through application of Eqs (1159) and (1160) (b) Assuming that the mixture is an ideal solution

[root@fedora-serverA ~]# fsck /dev/mapper/VolGroup00-LogVol02 fsck 1408 (12-Jul-2017) e2fsck 1408 (12-Jul-2017) /dev/mapper/VolGroup00-LogVol02: clean, 11/655360 files, 37896/655360 blocks

1126 Rationalize the following expression, valid at sufficiently low pressures, for estimating the fugacity coefficient: In q5 Z - 1 1127 For the system methane(l)/ethane(2)/propane(3) as a gas, estimate f l , f 2 , f 3 , $1, $2, and $3 at T = 37315 K (lOO C), P = 35 bar, yl = 021, and y2 = 043: (a) Through application of Eq (1161) (b) Assuming that the mixture is an ideal solution 1128 The excess Gibbs energy of a binary liquid mixture at T and P is given by:

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Figure 20-2. The MATH block can receive data wires for values of A and B. In Figure 20-2, I ve created a sample program that creates two random numbers (generated by two RANDOM blocks). Each RANDOM block uses its output data plug to run a wire into the A and B input data plugs on the MATH block. You should understand that you really can t do anything with the MATH block without having its data hub open. The reason for this is simple: no matter what operation (addition, subtraction, multiplication, or division) you choose to perform on values A and B, the answer can only be obtained from the Result data plug (using a data wire). Once values A and B have been added together, I want to see the answer on the LCD screen. To do this, I have to first convert the number to text. I drop in a NUMBER TO TEXT block (see Figure 20-3) and drag a data wire from the Result data plug on the MATH block into the Number data plug on the NUMBER TO TEXT block.

The preceding output shows that the file system is marked clean To forcefully check the file system and answer yes to all questions in spite of what your operating system (OS) thinks, type

(a) Find expressions for In yl and In y2 at T and P (b) Show that when these expressions are combined in accord with Eq (1195) the given equation for GE/ R T is recovered (c) Show that these expressions satisfy Eq (1 196), the GibbsIDuhem equation = 0 (d) Show that (d In yl/dxl)x,zl = (d In (e) Plot G E / R T , In yl, and In y2 as calculated by the given equation for GE/ R T and by the equations developed in (a) vs xl Label points In ylWand In y200 and show their values

First, relax The fsck check rarely finds problems that it cannot correct by itself When it does ask for human intervention, telling fsck to execute its default suggestion is often enough Very rarely does a single pass of e2fsck not clear up all problems On the rare occasions when a second run is needed, it should not turn up any more errors If it does, you are most likely facing a hardware failure Remember to start with the obvious: Check for reliable power and well-connected cables Anyone running SCSI systems should verify that they re using the correct type of terminator, that cables aren t too long, that SCSI IDs aren t conflicting, and that cable quality is adequate (SCSI is especially fussy about the quality of the cables)

1129 Show that yi = $i 1130 Given below are values of G ~ I mol-', H ~ I mol-', and J J mol-l K-l for some equimolar binary liquid mixtures at 29815 K (25 C) Estimate values of GE, H E , and sEat 32815 K (55 C) for one of the equimolar mixtures by two procedures: (I) Use all the data; (11) Assume C: = 0 Compare and discuss your results for the two procedures (a) Acetonelchloroform: GE = -622, H~ = -1920, CF = 42 (b) Acetoneln-hexane: G~ = 1095, H E = 1595, C = 33 : : (c) Benzenelisooctane: GE = 407, H E = 984, C = -27

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